Novel Metal Nanomaterials and Their Catalytic Applications
Abstract
:1. Introduction
2. Pt Nanocomplexes and Catalytic Applications in Organic Reactions
2.1. FePt@Cu NWs and the Catalytic Epoxidation
2.2. Pt@Fe2O3 NWs and the Selective Oxidation
2.3. Bimetallic Pt@Ir Nanocomplexes and the Catalytic Hydrogenation
3. Bimetallic Pt-M (Au and Pd) Nanocomplexes and Their Electro-Catalysis
3.1. Pt-Au Heterostructures and the Oxygen-Reduction Reaction
3.2. Au-Pt Bimetallic Nanocomplexes and the Electro-Catalysis
3.3. Pt/Pd Bimetallic Nanodendrites and the Electro-Catalysis
4. Au, Pd, Ag Nanostructures and Catalytic Applications in Organic Reactions
4.1. Au NWs and the Selective Oxidation
Entry | Solvent | Conversion (%) | Selectivity (%) | ||
---|---|---|---|---|---|
1 | DMF | 23.2 | 27.9 | 63.3 | 8.8 |
2 | 1,4-dioxane | 81.7 | 38.5 | 53.9 | 1.6 |
3 | m-xylene | 22.7 | 70.5 | 19.2 | 10.3 |
4 | p-xylene | 39.5 | 62.5 | 23.8 | 13.7 |
5 | chlorobenzene | 3.9 | 69.3 | 30.7 | - |
6 | heptane | 28.6 | 50.6 | 5.7 | 3.8 |
7 | toluene | 17.0 | 87.2 | 9.9 | 0.9 |
Entry | R | R1 | R2 | Conversion (%) | Selectivity (%) | |
---|---|---|---|---|---|---|
1 | H | H | H | 1.3 | 95.2 | 4.8 |
2 | o-CH3 | H | H | 4.3 | 62.1 | 37.9 |
3 | m-CH3 | H | H | 1.3 | 100 | - |
4 | p-CH3 | H | H | 3.4 | 82.4 | 17.6 |
5 | p-Cl | H | H | 1.0 | 100 | - |
6 | p-OCH3 | H | H | 0.6 | 100 | - |
7 | H | H | CH3 | 21.1 | 100 | - |
8 | p-NO2 | H | CH3 | 23.1 | 83.5 | 16.5 |
9 | p-OCH3 | H | CH3 | 1.3 | 70.8 | 29.2 |
10 | H | CH3 | CH3 | 47.9 | 62.9 | 37.1 |
4.2. CuO@Ag NWs and the Selective Oxidation
4.3. Pd Nanocatalysts and the Reductive Coupling Reactions
5. Perspectives and Challenges
Acknowledgments
Author Contributions
Conflicts of Interest
References
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Wang, J.; Gu, H. Novel Metal Nanomaterials and Their Catalytic Applications. Molecules 2015, 20, 17070-17092. https://doi.org/10.3390/molecules200917070
Wang J, Gu H. Novel Metal Nanomaterials and Their Catalytic Applications. Molecules. 2015; 20(9):17070-17092. https://doi.org/10.3390/molecules200917070
Chicago/Turabian StyleWang, Jiaqing, and Hongwei Gu. 2015. "Novel Metal Nanomaterials and Their Catalytic Applications" Molecules 20, no. 9: 17070-17092. https://doi.org/10.3390/molecules200917070