Insights into the Antimicrobial Activity of Hydrated Cobaltmolybdate Doped with Copper
Abstract
:1. Introduction
2. Results and Discussion
2.1. Structure of Materials
2.2. Spectroscopic Analysis
2.3. Thermal Analysis
2.4. Morphological and Elementary Analysis
2.5. Antibacterial Testing of Co1−xCuxMoO4·nH2O Materials
3. Materials and Methods
3.1. Reagents
3.2. Synthesis of CoMoO4·nH2O and Co1−xCuxMoO4·nH2O Microrods
3.3. Characterization
3.4. Antibacterial Test
4. Conclusions
Author Contributions
Funding
Data Availability Statement
Acknowledgments
Conflicts of Interest
Sample Availability
References
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Materials | a (Å) | b (Å) | c (Å) |
---|---|---|---|
CoMoO4·nH2O | 6.8265 | 6.9373 | 9.3645 |
Co0.97Cu0.03MoO4·nH2O | 6.8420 | 6.9374 | 9.3372 |
Co0.94Cu0.06MoO4·nH2O | 6.8510 | 6.9354 | 9.3342 |
Co0.88Cu0.12MoO4·nH2O | 6.8654 | 6.9272 | 9.3084 |
Morphology | Size | Reference | |
---|---|---|---|
Diameter | Length | ||
Nanorods | 10 nm | - | [8] |
sub-micrometricrods | 200–400 nm | >1 μm | [15] |
plate-like | - | 3–47 nm | [18] |
Microrods | 340 nm | 2.8 μm | [25] |
Nanorods | 50–100 nm | 1–3 μm | [26] |
Nanoparticles with spherical shape | 37 nm | 46–50 nm | [48] |
Material | Mass Percentage (%) | Molar Ratio | ||
---|---|---|---|---|
Co | Cu | Co | Cu | |
CoMoO4·1.03H2O | 100 | 0.00 | 1.00 | 0.00 |
Co0.97Cu0.03MoO4·H2O | 95.83 | 4.17 | 0.96 | 0.03 |
Co0.94Cu0.06MoO4·0.98H2O | 93.65 | 6.35 | 0.94 | 0.06 |
Co0.88Cu0.12MoO4·0.96H2O | 87.50 | 12.50 | 0.88 | 0.12 |
Material | Mass Percentage (%) | Molar Ratio | ||
---|---|---|---|---|
Co | Mo | Co | Mo | |
CoMoO4·1.03H2O | 42.73 | 57.27 | 1.00 | 0.80 |
Co0.97Cu0.03MoO4·H2O | 35.83 | 64.17 | 1.00 | 1.10 |
Co0.94Cu0.06MoO4·0.98H2O | 35.87 | 64.13 | 1.00 | 1.10 |
Co0.88Cu0.12MoO4·0.96H2O | 33.82 | 66.17 | 1.00 | 1.20 |
Bacterial Strains | Co1−xCuxMoO4·nH2O | |||
---|---|---|---|---|
x = 0.00 | x = 0.03 | x = 0.06 | x = 0.12 | |
MIC (mg L−1) | ||||
Escherichia coli | 0.39 | 1.56 | 0.78 | 0.78 |
Staphylococcus aureus | 0.19 | 0.78 | 0.78 | 0.78 |
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Silva, L.A.L.; Silva, A.A.L.; Rios, M.A.S.; Brito, M.P.; Araújo, A.R.; Silva, D.A.; Peña-Garcia, R.R.; Silva-Filho, E.C.; Magalhães, J.L.; Matos, J.M.E.; et al. Insights into the Antimicrobial Activity of Hydrated Cobaltmolybdate Doped with Copper. Molecules 2021, 26, 1267. https://doi.org/10.3390/molecules26051267
Silva LAL, Silva AAL, Rios MAS, Brito MP, Araújo AR, Silva DA, Peña-Garcia RR, Silva-Filho EC, Magalhães JL, Matos JME, et al. Insights into the Antimicrobial Activity of Hydrated Cobaltmolybdate Doped with Copper. Molecules. 2021; 26(5):1267. https://doi.org/10.3390/molecules26051267
Chicago/Turabian StyleSilva, Layane A. L., André A. L. Silva, Maria A. S. Rios, Manoel P. Brito, Alyne R. Araújo, Durcilene A. Silva, Ramón R. Peña-Garcia, Edson C. Silva-Filho, Janildo L. Magalhães, José M. E. Matos, and et al. 2021. "Insights into the Antimicrobial Activity of Hydrated Cobaltmolybdate Doped with Copper" Molecules 26, no. 5: 1267. https://doi.org/10.3390/molecules26051267