Synthesis and Characterization of Sol–Gelled Barium Zirconate as Novel MTA Radiopacifiers
Abstract
:1. Introduction
2. Materials and Methods
2.1. Preparation and Characterization of Barium Zirconate
2.2. Preparation and Evaluation of MTA-Like Cements
3. Results and Discussion
3.1. Preliminary Evaluation of Commercial Barium Ziconate Powder as Radiopacifier
3.2. Synthesis and Characterization of Sol–Gelled BaZrO3
3.3. Calcined BaZrO3 as Radiopacifier for MTAs
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
- Zhang, L.; Mei, L.; Wang, K.; Lv, Y.; Zhang, S.; Lian, Y.; Liu, X.; Ma, Z.; ** materials. Dent. Mater. 2014, 30, 709–715. [Google Scholar] [CrossRef]
- Camilleri, J. Tricalcium silicate cements with resins and alternative radiopacifiers. J. Endod. 2014, 40, 2030–2035. [Google Scholar] [CrossRef]
- Mureddu, M.; Bartolomé, J.F.; Lopez-Esteban, S.; Dore, M.; Enzo, S.; García, Á.; Garroni, S.; Pardo, L. Solid State Processing of BCZT Piezoceramics Using Ultra Low Synthesis and Sintering Temperatures. Materials 2023, 16, 945. [Google Scholar] [CrossRef]
- Bach, M.; Schemmel, T.; Hubálková, J.; Bühringer, M.; Jansen, H.; Aneziris, C.G. Effect of thermal treatment conditions on the solid-state synthesis of barium zirconate from barium carbonate and monoclinic zirconia. Ceram. Int. 2021, 47, 25839–25845. [Google Scholar] [CrossRef]
- Nayak, A.K.; Sasmal, A. Recent advance on fundamental properties and synthesis of barium zirconate for proton conducting ceramic fuel cell. J. Clean. Prod. 2023, 386, 135827. [Google Scholar] [CrossRef]
- Antončík, F.; Lojka, M.; Hlásek, T.; Sedmidubský, D.; Jankovský, O.; Bartůněk, V. The effective synthesis of large volumes of the ultrafine BaZrO3 nanoparticles. Mater. Chem. Phys. 2021, 259, 124047. [Google Scholar] [CrossRef]
- Guo, X.Z.; Wang, Z.C.; Song, J.; Yang, H. Sol gel synthesis of macroporous barium zirconate monoliths from ionic precursors via a phase separation route. J. Phys. Chem. Solids 2017, 102, 105–109. [Google Scholar] [CrossRef]
- Manju, P.; Ajith, M.R.; Jaiswal-Nagar, D. Synthesis and characterization of BaZrO3 nanoparticles by citrate-nitrate sol-gel auto-combustion technique: Systematic study for the formation of dense BaZrO3 ceramics. J. Eur. Ceram. Soc. 2019, 39, 3756–3767. [Google Scholar] [CrossRef]
- Babu, A.; Tirumalarao, D.; Das, S.; Dixit, V.; Sruthy, S.; Vijayan, V.; Jaiswal-Nagar, D. Effect of pH variation on citrate nitrate sol-gels obtained from auto-combustion method: Synthesis, calculations and characterisations of extremely dense BaZrO3 ceramic. Open Ceram. 2022, 12, 100303. [Google Scholar] [CrossRef]
- Zenou, V.Y.; Bakardjieva, S. Microstructural analysis of undoped and moderately sc-doped tio2 anatase nanoparticles using scherrer equation and debye function analysis. Mater. Charact. 2018, 144, 287–296. [Google Scholar] [CrossRef]
- Schneider, C.A.; Rasband, W.S.; Eliceiri, K.W. NIH Image to ImageJ: 25 years of image analysis. Nat. Methods 2012, 9, 671–675. [Google Scholar] [CrossRef]
- ISO 6876; Dental Root Canal Sealing Materials. ISO International Organization for Standardization: Geneva, Switzerland, 2001.
- Yu, P.; Cui, B.; Shi, Q. Preparation and characterization of BaTiO3 powders and ceramics by sol–gel process using oleic acid as surfactant. Mater. Sci. Eng. A 2008, 473, 34–41. [Google Scholar] [CrossRef]
- Rietveld, H. Line profiles of neutron powder-diffraction peaks for structure refinement. Acta Crystallogr. 1967, 22, 151–152. [Google Scholar] [CrossRef]
- Bruker AXS. Topas V2. 0. Profile and Structure Analysis Software for Powder Diffraction Data; User AMnula, Bruker AXS: Karlsruhe, Germany, 2000. [Google Scholar]
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Lin, H.-N.; Chen, M.-S.; Chang, P.-J.; Lee, Y.-C.; Chen, C.-Y.; Chiou, Y.-J.; Lin, C.-K. Synthesis and Characterization of Sol–Gelled Barium Zirconate as Novel MTA Radiopacifiers. Materials 2024, 17, 3015. https://doi.org/10.3390/ma17123015
Lin H-N, Chen M-S, Chang P-J, Lee Y-C, Chen C-Y, Chiou Y-J, Lin C-K. Synthesis and Characterization of Sol–Gelled Barium Zirconate as Novel MTA Radiopacifiers. Materials. 2024; 17(12):3015. https://doi.org/10.3390/ma17123015
Chicago/Turabian StyleLin, Hsiu-Na, May-Show Chen, Pei-Jung Chang, Yao-Chi Lee, Chin-Yi Chen, Yuh-**g Chiou, and Chung-Kwei Lin. 2024. "Synthesis and Characterization of Sol–Gelled Barium Zirconate as Novel MTA Radiopacifiers" Materials 17, no. 12: 3015. https://doi.org/10.3390/ma17123015