Simple Electrochemical Synthesis of Polyethylenimine-Encapsulated Ag Nanoparticles from Solid AgCl Applied in Catalytic Reduction of H2O2
Abstract
:1. Introduction
2. Results and Discussion
2.1. Electrochemical Reduction of AgCl to AgNPs
2.2. Characterization of AgNPs
2.3. Electrochemical Catalytic Effect of AgNPs for H2O2 Reduction
3. Materials and Methods
3.1. Materials
3.2. Characterization
3.3. Preparation of PEI-Encapsulated AgNPs
4. Conclusions
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Electrode | Silver Salt/Synthesis | Method | Detection Limit (μM) | Dynamic Range (μM) | Ref. |
---|---|---|---|---|---|
AgNPs/TPDT/GCE | AgNO3/ES | LSV | 0.5 | 0.5–3.5 | [44] |
AgNCs/PEI/GCE | AgNO3/CS | CA | 1.8 | 10–1440 | [45] |
AgNPs/PoPD/GCE | AgNO3/CS | CA | 1.5 | 6.0–67,300 | [46] |
AgNPs/collagen/GCE | AgNO3/ES | CA | 0.7 | 5.0–40,600 | [47] |
AgNPs/HDMA, PEG/SPCE | AgNO3/ES | CA | 1.5 | 10–180 | [48] |
AgNPs/PI/GCG | Commercial AgNPs | CA | 8.6 | 10–1000 | [49] |
AgNPs/PMES/GCE | AgNO3/ES | CA | 0.18 | 0.6–540 | [50] |
AgNPs/PEDOT/ITO | AgNO3/ES | CA | 7 | - | [51] |
AgNPs/PEI/GCE | AgCl/ES | CV | 1.66 | 2–1000 | This work |
Sample | Spiked (μM) | Found (μM) | Recovery (%) |
---|---|---|---|
1 | 2.5 | 2.42 | 96.8 |
2 | 2.5 | 2.37 | 94.8 |
3 | 2.5 | 2.59 | 103.6 |
Average | 2.5 | 2.46 | 98.4 |
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Kim, K.T.; Park, D.-S. Simple Electrochemical Synthesis of Polyethylenimine-Encapsulated Ag Nanoparticles from Solid AgCl Applied in Catalytic Reduction of H2O2. Catalysts 2020, 10, 1416. https://doi.org/10.3390/catal10121416
Kim KT, Park D-S. Simple Electrochemical Synthesis of Polyethylenimine-Encapsulated Ag Nanoparticles from Solid AgCl Applied in Catalytic Reduction of H2O2. Catalysts. 2020; 10(12):1416. https://doi.org/10.3390/catal10121416
Chicago/Turabian StyleKim, Kyung Tae, and Deog-Su Park. 2020. "Simple Electrochemical Synthesis of Polyethylenimine-Encapsulated Ag Nanoparticles from Solid AgCl Applied in Catalytic Reduction of H2O2" Catalysts 10, no. 12: 1416. https://doi.org/10.3390/catal10121416