Synthesis and Specific Properties of the Ceria and Ceria-Zirconia Nanocrystals and Their Aggregates Showing Outstanding Catalytic Activity in Redox Reactions—A Review
Abstract
:1. Introduction
2. Concise Description of the Crystal Structure of CeO2−y, ZrO2−y and ZrzCe1−zO2−y
3. Synthesis of the Ceria-Based Nanoparticles
4. Conclusions and Outlook
Author Contributions
Funding
Data Availability Statement
Conflicts of Interest
References
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Reaction | Catalyst | Ref. |
---|---|---|
CO oxidation | • RuO2/CeO2 with ultra-large mesopores | [1] |
• Au nanoparticles supported over nanoshaped CeO2 | [33] | |
• CuO/CeO2—different shaped nanocatalysts | [68] | |
• CuO-CeO2-ZrO2—flower-like morphology | [70] | |
• Au nanoparticles on {100}, {111} and {111} nanofacetted structures of CeO2 | [94] | |
• CeO2 catalysts | [85] | |
• Thermally reconstructed CeO2 nanocubes | [87] | |
• CeO2 nanocatalyst | [95] | |
• Nanostructured CoxCe1−xOy | [114] | |
• Cu-promoted CeO2 catalysts | [116] | |
• Doped CeO2—mesoporous flower-like morphology | [117] | |
• CeO2 nanoplates, nanotubes and nanorods | [127] | |
• CeO2 nanoflakes—graphene oxide as template | [131] | |
• Nanostructured CexZr1−xO2 | [137] | |
• Sonochemically prepared CeO2 nanoparticles | [139] | |
Diesel soot oxidation | • CeO2-ZrO2 nanocubes | [91] |
• CoOx-decorated CeO2 heterostructures | [108] | |
• CeO2/ZrO2 prepared by sol–gel method | [112] | |
• K-promoted Ce0.65Zr0.35O2 monolithic catalysts | [113] | |
Ethanol steam reforming | • Rh-Pd/CeO2 nanocubes and nanorods | [89] |
• Ir/CeO2 nanocatalysts | [93] | |
• Nanostructured CuO/CeO2/ZrO2/Al2O3 | [142] | |
Dry reforming of methane | • MOF-derived Ni/CeO2 catalyst | [21] |
• CeO2 nanoflakes—graphene oxide as sacrificial template | [131] | |
Low-temperature methanol combustion | • CoxCe1−xOy nanocatalysts | [3] |
• Nanocomposite catalysts MnxCe1−xO2/γ-Al2O3 | [5] | |
• Nanometric Ce1−x CuxO(2−δ) materials | [12,24,67] | |
• Nanowire hierarchical CeO2 micro-spheres | [6] | |
• Catalysts prepared by Ce-MOFs pyrolysis | [145] | |
Methane combustion | • Macroporous Ce0.6Zr0.3Y0.1O2 | [125] |
Combustion of polycyclic aromatic hydrocarbons | • Nanostructured CeO2 | [16] |
Fast pyrolysis of organic vapors | • Hierarchically structured CeO2 | [7] |
HCl oxidation with O2 to obtain Cl2 | • Mesoporous CeO2 | [15] |
NO reduction with CO | • Oxidized and reduced NiOx/CeO2 | [50] |
NH3-SCR | • Highly porous CeMnOx | [160] |
NH3 decomposition | • 3D-printed CeO2 structures loaded with Ni | [161] |
Carboxylative coupling using CO2 | • Mesoporous CeO2-supported Ag | [2] |
Dehydrogenation of ethylbenzene to styrene with CO2 | • CeO2-ZrO2/SBA-15 | [122] |
4-methylpentan-2-ol dehydration | • Nanophase CeO2-ZrO2 nanocubes | [153] |
Oxidation of benzyl alcohol with TBHP | • Mesoporous CeO2 | [4] |
Oxidation of benzyl alcohol with O2 | • Au-CeO2 catalysts | [100] |
Low-temperature bitumen upgrading | • Cr-substituted CeO2 nanoparticles | [120] |
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Dziembaj, R.; Molenda, M.; Chmielarz, L. Synthesis and Specific Properties of the Ceria and Ceria-Zirconia Nanocrystals and Their Aggregates Showing Outstanding Catalytic Activity in Redox Reactions—A Review. Catalysts 2023, 13, 1165. https://doi.org/10.3390/catal13081165
Dziembaj R, Molenda M, Chmielarz L. Synthesis and Specific Properties of the Ceria and Ceria-Zirconia Nanocrystals and Their Aggregates Showing Outstanding Catalytic Activity in Redox Reactions—A Review. Catalysts. 2023; 13(8):1165. https://doi.org/10.3390/catal13081165
Chicago/Turabian StyleDziembaj, Roman, Marcin Molenda, and Lucjan Chmielarz. 2023. "Synthesis and Specific Properties of the Ceria and Ceria-Zirconia Nanocrystals and Their Aggregates Showing Outstanding Catalytic Activity in Redox Reactions—A Review" Catalysts 13, no. 8: 1165. https://doi.org/10.3390/catal13081165