Trimetallic Oxides/GO Composites Optimized with Carbon Ions Radiations for Supercapacitive Electrodes
Abstract
:1. Introduction
2. Experimental Section
2.1. Synthesis of Graphene Oxide (GO)
2.2. Synthesis of Co3O4@MnO2@NiO/GO Electrodes
2.3. Irradiation of Co3O4@MnO2@NiO/GO Electrodes
2.4. Electrodes Characterizations
3. Results and Discussions
3.1. Structural Analysis
3.2. Surface/MorphologicalAnalysis
3.3. Electrochemistry Analysis
S/NO | Composites | Morphology | Specific Capacitance (Fg−1) | Current Density (Ag−1) | Potential Window (V) | Ref. |
---|---|---|---|---|---|---|
1. | Ni(OH)2-MnO2 | nanoflake core–shell | 355 | 0.5 | −0.1–0.9 | [75] |
2. | MnO2/NiO | nanoparticle | 681 | 1 | −1–0.9 | [76] |
3. | Ni–Mn | hedgehog-like hollow | 1016 | 0.5 | −0.2–1.0 | [77] |
4. | MnOOH/NiO | nanosheets | 1625 | 4 | 0–0.6 | [78] |
5. | Co3O4/NiO/MnO2 | nanospheres | 549 | 0.5 | −0.4–0.6 | [32] |
6. | Co3O4@MnO2/NGO | nanosheet | 347 | 0.5 | −0.34–0.34 | [36] |
7. | Co3O4@Pt@MnO2 | nanoflakes | 593 | 1 | 0–1.0 | [79] |
8. | NiO@Co3O4@MnO2 | nanoflakes | 792.5 | 2 | 0.35–0.5 | [80] |
9. | Co3O4@MnO2@PPy | nanoflakes | 977 | 1 | 0–0.8 | [81] |
10. | Co-Ni/Co3O4-NiO | Nano heterostructure | 2013 | 2.5 | 0.1–0.5 | [82] |
11. | Co3O4@MnO2 | nanowire | 413 | 0.5 | 0–0.6 | [31] |
12. | α-MnO2 and Co3O4 | Microspheres | 214.6 | 3 | [83] | |
13. | rGO/NiCo2O4@ZnCo2O4 | nanosheets | 1197 | 1 | 0–0.55 | [41] |
14. | Co3O4-MnO2-NiO | nanotubes | 2525 | 15 | −0.2–0.6 | [32] |
15. | MnCO3 QDs/NiH–Mn–CO3 | shell–nanoneedle | 2641.3 | 3 | −0.2–1.0 | [84] |
16. | NiO-Co3O4 | mesoporous | 324 | 2 | −0.5–0.5 | [85] |
17. | Co3O4@MnO2@NiO/GO | nanosphere | 215–732 | 1 | 0–0.8 | This work |
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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S/N | Electrode/ Radiation Dose (ions/cm2) | Dislocation Density (δ) (1017m) | Number of Crystallites in a Unit Surface Area (N) (10−12m) | Microstrain (ε) (10−2) |
---|---|---|---|---|
1 | Pristine | 0.56 | 1.79 | 4.20 |
2 | 2.25 × 1015 | 1.25 | 4.74 | 6.27 |
3 | 5.0 × 1015 | 2.07 | 7.29 | 8.18 |
4 | 7.25 × 1015 | 8.90 | 32.04 | 11.26 |
5 | 1.0 × 1016 | 9.10 | 33.66 | 13.77 |
Elements | Mass | % Weights by PIXE |
---|---|---|
Co | 54.94 | 22 |
Mn | 65.37 | 48 |
Ni | 63.50 | 30 |
Elements | Mass | K (ion) | Energy (MeV) | Channel |
---|---|---|---|---|
Co | 54.94 | 0.7885 | 1.618 | 1618.49 |
Mn | 65.37 | 0.7485 | 1.556 | 1556.06 |
Ni | 63.50 | 0.7540 | 1.630 | 1629.90 |
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Alshoaibi, A.; Awada, C.; Ahmed, F.; Obodo, R.M.; Maaza, M.; Ezema, F.I. Trimetallic Oxides/GO Composites Optimized with Carbon Ions Radiations for Supercapacitive Electrodes. Crystals 2022, 12, 874. https://doi.org/10.3390/cryst12060874
Alshoaibi A, Awada C, Ahmed F, Obodo RM, Maaza M, Ezema FI. Trimetallic Oxides/GO Composites Optimized with Carbon Ions Radiations for Supercapacitive Electrodes. Crystals. 2022; 12(6):874. https://doi.org/10.3390/cryst12060874
Chicago/Turabian StyleAlshoaibi, Adil, Chawki Awada, Faheem Ahmed, Raphael M. Obodo, Malik Maaza, and Fabian I. Ezema. 2022. "Trimetallic Oxides/GO Composites Optimized with Carbon Ions Radiations for Supercapacitive Electrodes" Crystals 12, no. 6: 874. https://doi.org/10.3390/cryst12060874