Crystal and Magnetic Structures in Layered, Transition Metal Dihalides and Trihalides
Abstract
:1. Introduction
2. Crystal Structures of Layered, Binary, Transition Metal Halides
2.1. MX Compounds
2.2. MX Compounds
3. Magnetic Structures of Layered, Binary, Transition Metal Halides
3.1. MX Compounds
3.1.1. TiX and ZrX
3.1.2. VX
3.1.3. MnX
3.1.4. FeX
3.1.5. CoX
3.1.6. NiX
3.2. MX Compounds
3.2.1. VX
3.2.2. CrX
3.2.3. FeX
3.2.4. RuX
4. Summary and Conclusions
Acknowledgments
Conflicts of Interest
References
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Compound | Structure Type | Reference | in Plane | Layer | Magnetic Order | Moments | , (K) | , (K) |
---|---|---|---|---|---|---|---|---|
Distance (Å) | Spacing (Å) | in Layer | ||||||
TiCl | CdI () | [44] | 3.56 | 5.88 | AFM | – | 85 | −702 |
TiBr | CdI () | [45] | 3.63 | 6.49 | – | – | – | – |
TiI | CdI () | [46] | 4.11 | 6.82 | – | – | – | – |
VCl | CdI () | [47] | 3.6 | 5.83 | AFM | 120 | 36 | −565, −437 |
VBr | CdI () | [46] | 3.77 | 6.18 | AFM | 120 | 30 | −335 |
VI | CdI () | [48] | 4.06 | 6.76 | AFM | – | 16.3, 15 | −143 |
MnCl | CdCl () | [49] | 3.71 | 5.86 | AFM or HM | stripe or HM | 2.0, 1.8 | −3.3 |
MnBr * | CdI () | [50] | 3.89 | 6.27 | AFM | stripe | 2.3, 2.16 | – |
MnI | CdI () | [51] | 4.16 | 6.82 | HM | HM | 3.95, 3.8, 3.45 | – |
FeCl | CdCl () | [52] | 3.6 | 5.83 | AFM | FM ⊥ | 24 | 9 (), 21 (⊥) |
FeBr | CdI () | [53] | 3.78 | 6.23 | AFM | FM ⊥ | 14 | −3.0 (), 3.5 (⊥) |
FeI | CdI () | [54] | 4.03 | 6.75 | AFM | stripe ⊥ | 9 | 24 (), 21.5 (⊥) |
CoCl | CdCl () | [55] | 3.54 | 5.81 | AFM | FM | 25 | 38 |
CoBr | CdI () | [56] | 3.69 | 6.12 | AFM | FM | 19 | – |
CoI | CdI () | [51] | 3.96 | 6.65 | HM | HM | 11 | – |
NiCl | CdCl () | [57] | 3.48 | 5.8 | AFM | FM | 52 | 68 |
NiBr | CdCl () | [58] | 3.7 | 6.09 | AFM, HM | FM , HM | 52, 23 | – |
NiI * | CdCl () | [59] | 3.9 | 6.54 | HM | HM | 75 | – |
ZrCl | MoS () | [60] | 3.38 | 6.45 | – | – | – | – |
ZrI | MoTe () | [61] | 3.18, 3.74, 4.65 | 7.43 | – | – | – | – |
ZrI | WTe2 () | [62] | 3.19, 3.74, 4.65 | 7.44 |
Compound | Structure Type | Reference | in Plane | Layer | Magnetic Order | Moments | or , (K) | , (K) |
---|---|---|---|---|---|---|---|---|
Distance (Å) | Spacing (Å) | in Layer | ||||||
TiCl * | BiI () | [28] | 3.53 | 5.83 | – | – | – | – |
TiCl * | TiO () | [70] | 3.55 | 5.86 | ||||
TiBr * | BiI () | [71] | 3.74 | 6.21 | – | – | – | – |
VCl | BiI () | [28] | 3.47 | 5.78 | AFM | – | ∼20 | −30 |
VBr | BiI () | [72] | 3.7 | 6.21 | – | – | – | – |
CrCl * | AlCl () | [73] | 3.44, 3.44 | 5.80 | AFM | FM | 15.5, 16.8 | 27 |
CrBr * | BiI () | [74] | 3.64 | 6.11 | FM | FM ⊥ | 37 | 47 |
CrI * | AlCl () | [16] | 3.96, 3.97 | 6.62 | FM | FM ⊥ | 61 | 70 |
FeCl | BiI () | [75] | 3.50 | 5.80 | HM | HM | 9–10 | −11.5 |
FeCl | TiO () | [76] | 3.50 | 5.80 | ||||
FeCl | FeCl () | [76] | 3.50 | 5.81 | ||||
FeBr | BiI () | [77] | 3.69 | 6.13 | AFM | – | 15.7 | – |
MoCl | AlCl () | [78] | 2.76, 3.71 | 5.99 | – | – | – | – |
TcCl | AlCl () | [79] | 2.86, 3.60 | 5.86 | – | – | – | – |
RuCl * | AlCl () | [80] | 3.45, 3.45 | 5.69 | AFM | zig-zag canted | 7–8, 13–14 | 37 (), −150(⊥) |
RuCl * | TiO () | [81] | 3.45 | 5.72 | ||||
RuCl * | CrCl () | [82] | 3.44, 3.45 | 5.73 | ||||
RhCl | AlCl () | [83] | 3.44, 3.43 | 5.70 | – | – | – | – |
RhBr | AlCl () | [84] | 3.62, 3.62 | 6.00 | – | – | – | – |
RhI | AlCl () | [84] | 3.91, 3.90 | 6.45 | – | – | – | – |
IrCl | AlCl () | [85] | 3.46, 3.45 | 5.64 | – | – | – | – |
IrBr | AlCl () | [86] | 3.67, 3.64 | 6.01 | – | – | – | – |
IrI | AlCl () | [86] | – | 6.54 | – | – | – | – |
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McGuire, M.A. Crystal and Magnetic Structures in Layered, Transition Metal Dihalides and Trihalides. Crystals 2017, 7, 121. https://doi.org/10.3390/cryst7050121
McGuire MA. Crystal and Magnetic Structures in Layered, Transition Metal Dihalides and Trihalides. Crystals. 2017; 7(5):121. https://doi.org/10.3390/cryst7050121
Chicago/Turabian StyleMcGuire, Michael A. 2017. "Crystal and Magnetic Structures in Layered, Transition Metal Dihalides and Trihalides" Crystals 7, no. 5: 121. https://doi.org/10.3390/cryst7050121