Low-Cost Plant-Based Metal and Metal Oxide Nanoparticle Synthesis and Their Use in Optical and Electrochemical (Bio)Sensors
Abstract
:1. Introduction
2. Sensors and Biosensors
3. Green Synthesis of Metallic Nanoparticles from Plant Extract
4. Metallic Nanoparticle-Based Sensors
4.1. Ag Nanoparticles
4.1.1. Optical (Bio)Sensors Based on Ag Nanoparticles
- 1.
- Detection of Hg2+ as a water pollutant by AgNPs.
- 2.
- Detection of ammonia by AgNPs
- 3.
- Detection of different heavy metal ions as water pollutants by AgNPs
- 4.
- Detection of H2O2 by AgNPs
4.1.2. Ag-Based Electrochemical (Bio)Sensors for Pharmaceutical and Bioactive Molecules
4.2. Au Nanoparticles
4.2.1. Optical Sensors Based on Au Nanoparticles
4.2.2. Electrochemical Biosensor Based on Au Nanoparticles
4.3. Non-Noble Metals
4.3.1. Ni and NiO Nanoparticles
4.3.2. Zn and ZnO Nanoparticles
MNP Systems | Type of Extract | Detected Analyte | Linear Range | LOD | Reference |
---|---|---|---|---|---|
AgNP–Hedy-arum | Hedysarum aqueous; Soap-root extract | Hg(II) | 10–100 µM | 2.2 μM | [60] |
AgNP–AB | Agaricus Bispores | Hg(II) | 10–90 µM | 2.1 μM | [61] |
AgNP–CLW | Cauliflower-Brassica oleracea var. botrytis | Hg(II) | 0.49 μM | [62] | |
AgNP–Aw | Achillea Wilhelmsii | Hg(II) | 100 nM–100 µM 10–700 µM | 28 nM on solution 0.3 μM on paper | [63] |
AgNP–AC | Acacia chundra | Hg(II) | 0.28 μM | [64] | |
AgNP–CJ | Citrus japonica (CJ) | Hg(II) | 0.3–7.3 µM | 0.09 μM | [65] |
AgNP–MD | Mimosa diplotricha | Hg(II) | 5–45 μM | 1.46 μM | [66] |
AgNP–M | Molasses | Hg(II) | 0.01–1 μM | 0.02 μM | [67] |
AgNP–TC | Terminalia chebula | Ammonia | 0–100 ppm | 50 ppm | [68] |
AgNP–GG | Cyamopsis tetragonaloba | Ammonia | 1–50 ppm | 1 ppm | [69] |
AgNP–SG | Sugarcane leaves | H2O2 | 0–200 mM | 30 mM | [70] |
Ammonia | 0–50 ppm | 5 ppm | |||
AgNP–MOF | Moringa oleifera flower | Cu(IV) | 1–12 mM | 0.249 mM | [71] |
AgNP–AS | Allium sativum | Cd(II) | 10–90 μM | 0.277 μM | [73] |
AgNP–LE | Lycopersicon esculentum | Cr(III) | 10–90 μM | 0.804 μM | [74] |
AgNP–LBG | Ceratonia siliqua | H2O2 | 0.01–1 mM | 0.01 mM | [75] |
AgNP–Algae | Noctiluca scintillans | H2O2 | 4.70–32 nM | 1.34 nM | [76] |
AgNP–rGOx | Tea | H2O2 | 0.002–20 mM | 0.73 μM | [80] |
Ag–GO | Andrographis paniculata | H2O2 | 0–15 μM | 2.65 μM | [81] |
AgNPs–GCE | C. sempervirens pollen | H2O2 | 5 μM–2.5 mM | 0.23 μM | [82] |
AgNP–xGnP | Araucaria angustifolia | paracetamol | 4.98 × 10−6–3.38 × 10−5 mol L−1 | 8.50 × 10−8 mol L−1 | [83] |
AgNps/f-MWCNT | Cinnamomum tamala | BPA | 3.9 fM–102.4 nM | 0.38 nM | [84] |
AgNps/f-MWCNT | Moringa oleifera extract | BPA | 0.3–8 µM | 0.22 µM | [86] |
AuNP–GG | Guar Gum (GG) | ammonia | - | 1 ppb | [89] |
AuNP–CMGK | Gum Karaya | Cu(II) | 10–1000 nM | 10 nM | [90] |
AuNP–WTB | Willow tree bark | cysteine | 2 × 10−7–20 × 10−7 mol/L | 0.63 × 10−7 mol/L | [91] |
AuNP–tea | Green tea | CD44 antigen | 42.9 aM–100 nM | 0.111 pM | [92] |
AuNP–tea | Green tea | Acetamiprid | 3.0 × 10−8–4.0 × 10−6 M | 1.76 × 10−8 M | [93] |
AuNP–rGO | E. tereticornis | L-tryptophan | 0.5–500 µmol/L | 0.39 µmol/L | [94] |
AuNP–rGO | Rose | glucose | 1–8 mM | 10 µM | [95] |
AuNP–GO | Bischofia javanica Blume | chloramphenicol | 1.5–2.95 μM | 0.25 μM | [96] |
AuNP–CNT–SPE | Sargassum sp. | glucose | 1–7 mM | 50 µM | [97] |
NiNP–NS | Nigella sativa | glucose | 50–600 µM | 3.2 µM | [98] |
NiONP–TS | Trigonella subenervis | glucose | 10–200 μM | 3.2 µM | [99] |
NiNP–PP | Pomelo Peel | glucose | 15.84 μM–6.48 mM | 4.8 µM | [100] |
NiONP–TE | Tagetes erecta L. | glucose | 0.1–1 mM | <83 µM | [101] |
GCE/ZnO–NDCS/GOx | peach juice | glucose | 0.2–12 mM | 6.3 µM | [107] |
GCE/MWCNTs/ZnO NPs | Carica papaya | Silymarin | 0.014–0.152 mg/L | 0.062 mg/L | [108] |
GPE/ZnO NPs | Citrus sinensis | formaldehyde | 0–100 mM | 18 μM | [109] |
ZnONPs | Ixora Coccinea | Ethanol | 40–800 ppm | 200 ppm | [111] |
5. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Ciobotaru, I.C.; Oprea, D.; Ciobotaru, C.C.; Enache, T.A. Low-Cost Plant-Based Metal and Metal Oxide Nanoparticle Synthesis and Their Use in Optical and Electrochemical (Bio)Sensors. Biosensors 2023, 13, 1031. https://doi.org/10.3390/bios13121031
Ciobotaru IC, Oprea D, Ciobotaru CC, Enache TA. Low-Cost Plant-Based Metal and Metal Oxide Nanoparticle Synthesis and Their Use in Optical and Electrochemical (Bio)Sensors. Biosensors. 2023; 13(12):1031. https://doi.org/10.3390/bios13121031
Chicago/Turabian StyleCiobotaru, Iulia Corina, Daniela Oprea, Constantin Claudiu Ciobotaru, and Teodor Adrian Enache. 2023. "Low-Cost Plant-Based Metal and Metal Oxide Nanoparticle Synthesis and Their Use in Optical and Electrochemical (Bio)Sensors" Biosensors 13, no. 12: 1031. https://doi.org/10.3390/bios13121031