Metal Complexes with Schiff Bases as Antimicrobials and Catalysts
Abstract
:1. Introduction
2. SBs Complexes with Metals as Antimicrobials
2.1. SBs Complexes with Transition Metals
Structure | Compd | MIC or IZD | Ref. |
---|---|---|---|
C19H16O2N3 Cl2Cr (1) | IZD = 23 mm (E. coli) IZD = 24 mm (S. subtilis) IZD = 22 mm (A. niger) | Aroua et al. (2023) [66] | |
C19H18O3N3 ClMn (2) | IZD = 26 mm (E. coli) IZD = 24 mm (S. subtilis) IZD = 25 mm (A. niger) | Aroua et al. (2023) [66] | |
(Co(L)(Cl)2(H2O)2 (3) | IZD = 15 mm (S. enterica ser. thypi at 30 mg/mL) IZD = 19 mm (C. albicans at 30 mg/mL) | Alorini et al. (2023) [67] | |
4 | MIC = 25 ± 1.10 mm (S. aureus) MIC = 28 ± 1.10 mm (P. aeruginosa) | Al-Janabi et al. (2023) [68] | |
5 | MIC = 0.0225 µmol/mL (S. aureus MTCC 2901) MIC = 0.0112 µmol/mL (B. subtilis NCIM 2063) MIC = 0.0225 µmol/mL (E. coli MTCC 732) MIC = 0.0112 µmol/mL (P. aeruginosa MTCC 424) MIC = 0.0056 µmol/mL (C. albicans MTCC 227) MIC = 0.0112 µmol/mL (A. niger MTCC 9933) | Devi et al. (2022) [70] | |
6 | MIC = 0.0223 µmol/mL (S. aureus MTCC 2901) MIC = 0.0223 µmol/mL (B. subtilis NCIM 2063) MIC = 0.0223 µmol/mL (E. coli MTCC 732) MIC = 0.0111 µmol/mL (P. aeruginosa MTCC 424) MIC = 0.0055 µmol/mL (C. albicans MTCC 227) MIC = 0.0111 µmol/mL (A. niger MTCC 9933) | Devi et al. (2022) [70] | |
7 | MIC = 0.0114 µmol/mL (S. aureus MTCC 2901) MIC = 0.0114 µmol/mL (B. subtilis NCIM 2063) MIC = 0.0228 µmol/mL (E. coli MTCC 732) MIC = 0.0228 µmol/mL (P. aeruginosa MTCC 424) MIC = 0.0056 µmol/mL (C. albicans MTCC 227) MIC = 0.0114 µmol/mL (A. niger MTCC 9933) | Devi et al. (2022) [70] | |
8 | MIC = 0.0113 µmol/mL (S. aureus MTCC 2901) MIC = 0.0226 µmol/mL (B. subtilis NCIM 2063) MIC = 0.0226 µmol/mL (E. coli MTCC 732) MIC = 0.0226 µmol/mL (P. aeruginosa MTCC 424) MIC = 0.0055 µmol/mL (C. albicans MTCC 227) MIC = 0.0113 µmol/mL (A. niger MTCC 9933) | Devi et al. (2022) [70] | |
Z2Zn (9) | IZD = 15 mm (M. luteus ATCC 934) IZD = 21 mm (S. aureus ATCC 29213) | Al-Shboul et al. (2022) [71] | |
Z3Zn (10) | IZD = 25 mm (M. luteus ATCC 934) IZD = 18 mm (S. aureus ATCC 29213) | Al-Shboul et al. (2022) [71] | |
Z4Fe (11) | IZD = 20 mm (S. aureus ATCC 29213) | Al-Shboul et al. (2022) [71] | |
Z1Cu (12) | IZD = 10 mm (E. coli ATCC 25922) | Al-Shboul et al. (2022) [71] | |
Z3Cu (13) | IZD = 20 mm (E. coli ATCC 25922) | Al-Shboul et al. (2022) [71] | |
NiL (14) | IZD = 31.6 ± 0.6 mm (E. coli ATCC 10536) IZD = 20.6 ± 0.6 mm (K. pneumoniae ATCC 10031) IZD = 20.3 ± 0.6 mm (S. aureus ATCC 13565) IZD = 19.6 ± 0.6 mm (S. mutans ATCC 25175) | Abdel-Rahman et al. (2022) [72] | |
LaL (15) | IZD = 21.3 ± 0.6 mm (E. coli ATCC 10536) IZD = not active (K. pneumoniae ATCC 10031) IZD = 20.3 ± 0.6 mm (S. aureus ATCC 13565) IZD = 17.9 ± 0.5 mm (S. mutans ATCC 25175) | Abdel-Rahman et al. (2022) [72] | |
16 | IZD = 20 ± 0.21 mm (B. amyloliquefaciens) IZD = 19 ± 0.16 mm (E. coli) IZD = 18 ± 0.18 mm (S. rolfsii) IZD = 18 ± 0.15 mm (M. phaseolina) | Daravath et al. (2022) [74] | |
17 | IZD = 17 ± 0.14 mm (B. amyloliquefaciens) IZD = 16 ± 0.21 mm (E. coli) IZD = 15 ± 0.24 mm (S. rolfsii) IZD = 16 ± 0.16 mm (M. phaseolina) | Daravath et al. (2022) [74] | |
18 | IZD = 16 ± 0.18 mm (B. amyloliquefaciens) IZD = 16 ± 0.15 mm (E. coli) IZD = 14 ± 0.15 mm (S. rolfsii) IZD = 15 ± 0.19 mm (M. phaseolina) | Daravath et al. (2022) [74] | |
Z1 (19) | IZD = 16 mm (S. aureus ATCC 25923) IZD = 15 mm (B. cereus ATCC 11778) IZD = 11 mm (E coli ATCC 25922) IZD = 12 mm (P. aeruginosa ATCC 15442) PMMI = 22.8 mm (A. brasiliensis ATCC 16404) IZD = 22 mm (C. albicans ATCC 10231) | Kargar et al. (2022) [65] | |
Z2 (20) | IZD = 18 mm (S. aureus ATCC 25923) IZD = 14 mm (B. cereus ATCC 11778) IZD = 13 mm (E coli ATCC 25922) IZD = 12 mm (P. aeruginosa ATCC 15442) PMMI = 22.8 mm (A. brasiliensis ATCC 16404) IZD = 23 mm (C. albicans ATCC 10231) | Kargar et al. (2022) [65] | |
[ZnLBr]ClO4 (21) | IZD = 14 mm (S. aureus) IZD = 15 mm (B. subtilis) IZD = 19 mm (L. monocytogenes) IZD = 34 mm (E. coli) IZD = 28 mm (K. oxytoca) IZD = 21 (S. thypimurium) | Hajari et al. (2022) [75] | |
[MnLBr]ClO4 (22) | IZD = 12 mm (S. aureus) IZD = 22 mm (B. subtilis) IZD = 17 mm (L. monocytogenes) IZD = 29 mm (E. coli) IZD = 22 mm (K. oxytoca) IZD = 19 (S. thypimurium) | Hajari et al. (2022) [75] | |
[CdLBr]ClO4 (23) | IZD = 17 mm (S. aureus) IZD = 17 mm (B. subtilis) IZD = 16 mm (L. monocytogenes) IZD = 24 mm (E. coli) IZD = 18 mm (K. oxytoca) IZD = 21 (S. thypimurium) | Hajari et al. (2022) [75] | |
II (24) | IZD between 11 and 12 mm (B. subtilis) IZD between11 and 12 mm (F.O. Lycopersicum) | Jyothi et al. (2022) [76] | |
4a (25) | MIC = 4 µg/mL (S. aureus) MIC = 8 µg/mL (B. subtilis) MIC = 8 µg/mL (E. coli) MIC = 8 µg/mL (P. aeruginosa) | Li et al. (2022) [77] | |
5a (26) | MIC = 4 µg/mL (S. aureus) MIC = 4 µg/mL (B. subtilis) MIC = 4 µg/mL (E. coli) MIC = 8 µg/mL (P. aeruginosa) | Li et al. (2022) [77] | |
27 | MIC = 0.01080 μmol/mL (B. subtilis MTCC 441) MIC = 0.01080 μmol/mL (E. coli MTCC 732) MIC = 0.01080 μmol/mL (P. aeruginosa MTCC 424) MIC = 0.01080 μmol/mL (C. albicans MTCC 227) MIC = 0.01080 μmol/mL (A. niger MTCC 9933) | Saroya et al. (2022) [78] |
2.2. SBs Complexes with Inner Transition Metals (Lanthanides and Actinides) as Antimicrobials
3. Chitosan SBs Complexes as Antimicrobials
4. Metal Complexes with SBs with Catalytic Activity
5. Summary
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Structure | Compd | MIC or IZD | Ref. |
---|---|---|---|
Schiff-Er (28) | IZD = 21 mm (P. aeruginosa) IZD = 23 mm (S. aureus) | Andiappan et al. (2023) [79] | |
Schiff-Pr (29) | IZD = 24 mm (P. aeruginosa) IZD = 24 mm (S. aureus) | Andiappan et al. (2023) [79] | |
Schiff-Yb (30) | IZD = 22 mm (P. aeruginosa) IZD = 20 mm (S. aureus) | Andiappan et al. (2023) [79] | |
La (31) | MIC = 0.75 mg/mL (S. aureus ATCC 29213) MIC = 3 mg/mL (S. aureus ATCC 33591) MIC = 3 mg/mL (E. coli ATCC 25922) MIC = 1.5 mg/mL (P. aeruginosa ATCC 27853) MIC = 1.5 mg/mL (C. albicans ATCC 10231) | Alqasaimeh et al. (2023) [80] | |
Lb (32) | MIC = 0.75 mg/mL (S. aureus ATCC 29213) MIC = 3 mg/mL (S. aureus ATCC 33591) MIC = 3 mg/mL (E. coli ATCC 25922) MIC = 1.5 mg/mL (P. aeruginosa ATCC 27853) MIC = 1.5 mg/mL (C. albicans ATCC 10231) | Alqasaimeh et al. (2023) [80] | |
Lc (33) | MIC = 0.75 mg/mL (S. aureus ATCC 29213) MIC = 3 mg/mL (S. aureus ATCC 33591) MIC = 3 mg/mL (E. coli ATCC 25922) MIC = 1.5 mg/mL (P. aeruginosa ATCC 27853) MIC = 0.75 mg/mL (C. albicans ATCC 10231) | Alqasaimeh et al. (2023) [80] | |
[La2(C26H28O2N6)2(NO3)6]·6H2O (34) | IZD = 32–35 mm (S. aureus) IZD = 24–28 mm (S. subtilis) IZD = 18–20 mm (E. coli) IZD = 18–20 mm (K. pneumoniae) | Hussein et al. (2023) [81] | |
[Gd2(C26H28O2N6)2(NO3)6]·6H2O (35) | IZD = 21–35 mm (S. aureus) IZD = 24–28 mm (S. subtilis) IZD = 21–24 mm (E. coli) IZD = 21–24 mm (K. pneumoniae) | Hussein et al. (2023) [81] | |
[Er2(C26H28O2N6)2(NO3)6]·6H2O (36) | IZD = 28–32 mm (S. aureus) IZD = 28–32 mm (S. subtilis) IZD = 18–20 mm (E. coli) IZD = 24–28 mm (K. pneumoniae) | Hussein et al. (2023) [81] | |
UrO2SV (37) | IZD = 18 mm (S. aureus) IZD = 15 mm (E. faecalis) IZD = 20 mm (K. pneumoniae) IZD = 15 mm (P. aeruginosa) | Awolope et al. (2023) [82] | |
ZrOSV (38) | IZD = 15 mm (S. aureus) IZD = 17 mm (E. faecalis) IZD = 17 mm (K. pneumoniae) IZD = 16 mm (P. aeruginosa) | Awolope et al. (2023) [82] |
Structure | Compd | MIC or IZD | Ref. |
---|---|---|---|
CS-CT-CCa (39) | MIC = 128 μg/mL (V. parahaemolyticus ATCC 17802) | Tao et al. (2023) [103] | |
Ru(CVSB)(H2O)2]Cl2 (40) | IZD = 11 mm (A. flavus) IZD = 12 mm (A. niger) IZD = 11 mm (P. chryogenum) IZD = 10 mm (F. oxysporum) IZD = 12 mm (T. viride) | Amirthaganesan et al. (2022) [104] | |
Ru(CSSB)(H2O)2]Cl2 (41) | IZD = 14 mm (A. flavus) IZD = 12 mm (A. niger) IZD = 10 mm (P. chryogenum) IZD = 11 mm (F. oxysporum) IZD = 10 mm (T. viride) | Amirthaganesan et al. (2022) [104] | |
Ru(COSB)(H2O)2]Cl2 (42) | IZD = 12 mm (A. flavus) IZD = 12 mm (A. niger) IZD = 11 mm (P. chryogenum) IZD = 10 mm (F. oxysporum) IZD = 12 mm (T. viride) | Amirthaganesan et al. (2022) [104] |
Structure | Compd | Catalyzed Reactions | Ref. |
---|---|---|---|
[Zn2(L1)2(N3)2] (43) | Synthesis of tetrazoles | Bikas et al. (2023) [105] | |
[Zn2(L2)2(N3)2] (44) | Synthesis of tetrazoles | Bikas et al. (2023) [105] | |
CuL2 (45) | Oxidation of secondary alcohols | Neshat et al. (2023) [106] | |
Cu(BDC-NH2)@Schiff base Pd(II) (46) | C–N coupling reactions | Rabiei et al. (2023) [107] | |
V(O)-5NSA-MCM-41 (47) | Oxidative coupling of thiols and oxidation of sulfides | Jabbari et al. (2023) [108] | |
Fe3O4@CS@Schiffbase@Cu (48) | A3 coupling reaction under microwave irradiation | Hasan et al. (2023) [109] |
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Iacopetta, D.; Ceramella, J.; Catalano, A.; Mariconda, A.; Giuzio, F.; Saturnino, C.; Longo, P.; Sinicropi, M.S. Metal Complexes with Schiff Bases as Antimicrobials and Catalysts. Inorganics 2023, 11, 320. https://doi.org/10.3390/inorganics11080320
Iacopetta D, Ceramella J, Catalano A, Mariconda A, Giuzio F, Saturnino C, Longo P, Sinicropi MS. Metal Complexes with Schiff Bases as Antimicrobials and Catalysts. Inorganics. 2023; 11(8):320. https://doi.org/10.3390/inorganics11080320
Chicago/Turabian StyleIacopetta, Domenico, Jessica Ceramella, Alessia Catalano, Annaluisa Mariconda, Federica Giuzio, Carmela Saturnino, Pasquale Longo, and Maria Stefania Sinicropi. 2023. "Metal Complexes with Schiff Bases as Antimicrobials and Catalysts" Inorganics 11, no. 8: 320. https://doi.org/10.3390/inorganics11080320