Metal Substitution versus Oxygen-Storage Modifier to Regulate the Oxygen Redox Reactions in Sodium-Deficient Three-Layered Oxides
Abstract
:1. Introduction
2. Results and Discussions
2.1. Structure of Metal-Substituted and CeO2-Treated Oxides
2.2. Electrochemical Behavior of Metal-Substituted and CeO2-Treated Oxides
2.2.1. Sodium-Ion Cells
2.2.2. Lithium-Ion Cells
2.3. Surface Deposition after Na+ and Li+ Intercalation
2.3.1. Sodium Electrolyte
2.3.2. Lithium Electrolyte
3. Materials and Methods
3.1. Materials
3.2. Methods
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Samples | a ± 0.0001, Å | с ± 0.002, Å | V ± 0.02, Å3 |
---|---|---|---|
NNM | 2.8867 | 16.7692 | 121.01 |
NM16 | 2.8889 | 16.7789 | 121.27 |
NT16 | 2.8992 | 16.8237 | 122.46 |
CNNM | 2.8872 | 16.7724 | 121.09 |
CNM16 | 2.8867 | 16.7732 | 121.29 |
CNT16 | 2.8889 | 16.8236 | 122.54 |
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Kalapsazova, M.; Kukeva, R.; Zhecheva, E.; Stoyanova, R. Metal Substitution versus Oxygen-Storage Modifier to Regulate the Oxygen Redox Reactions in Sodium-Deficient Three-Layered Oxides. Batteries 2022, 8, 56. https://doi.org/10.3390/batteries8060056
Kalapsazova M, Kukeva R, Zhecheva E, Stoyanova R. Metal Substitution versus Oxygen-Storage Modifier to Regulate the Oxygen Redox Reactions in Sodium-Deficient Three-Layered Oxides. Batteries. 2022; 8(6):56. https://doi.org/10.3390/batteries8060056
Chicago/Turabian StyleKalapsazova, Mariya, Rositsa Kukeva, Ekaterina Zhecheva, and Radostina Stoyanova. 2022. "Metal Substitution versus Oxygen-Storage Modifier to Regulate the Oxygen Redox Reactions in Sodium-Deficient Three-Layered Oxides" Batteries 8, no. 6: 56. https://doi.org/10.3390/batteries8060056