Electrocatalytic Properties of Quasi-2D Oxides LaSrMn_0.5M_0.5O₄ (M = Co, Ni, Cu, and Zn) for Hydrogen and Oxygen Evolution Reactions

Designing cost-effective and highly efficient electrocatalysts for water splitting is a significant challenge. We have systematically investigated a series of quasi-2D oxides, LaSrMn_0.5M_0.5O₄ (M = Co, Ni, Cu, Zn), to enhance the electrocatalytic properties of the two half-reactions of water-splitting, namely oxygen and hydrogen evolution reactions (OER and HER). The four materials are isostructural, as confirmed by Rietveld refinements with X-ray diffraction. The oxygen contents and metal valence states were determined by iodometric titrations and X-ray photoelectron spectroscopy. Electrical conductivity measurements in a wide range of temperatures revealed semiconducting behavior for all four materials. Electrocatalytic properties were studied for both half-reactions of water-splitting, namely, oxygen-evolution and hydrogen-evolution reactions (OER and HER). For the four materials, the trends in both OER and HER were the same, which also matched the trend in electrical conductivities. Among them, LaSrMn_0.5Co_0.5O₄ showed the best bifunctional electrocatalytic activity for both OER and HER, which may be attributed to its higher electrical conductivity and favorable electron configuration.